Hiroshima University, Graduate School of Engineering 

Polymer Technology Lab.

Nakai・Gotoh Lab.

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 Japanese
 

  A polymer gel is a cross-linked three dimentional polymer networks that contains liquids in its internal space. It is a soft matter intermediate between a solid and a liquid. The gel shows discontinuous volume change when a external stimuli such as temperature, light and electric field, is imposed upon it. It is called a stimuli responsiveness.

  The polymer gel  swells or shrinks when external condition such as  ion strength or solvent composition is changed. It is called a phase transition. The phase transition in gels caused by four fundamental interactions, i.e. hydrogen bonding, hydrophobic interaction, van der Waals interaction and ionic interaction between ionized groups.

  There are many potential applications of the polymer gels  such as the separation of solutes or metal ions, immobilization of enzymes and drug delivery system. New application also has been developed, in which gel networks are used as a reaction, separation and/or chemo-mechanical energy transformation media, for example, adsorbents, membranes, chromatography and preparation of fine particles in the gel networks.

    The optical properties of ZnO nanoparticles are substantially different from those of bulk crystalline ZnO. The luminescence spectra are dependent on the crystalline size (quantum size effect).
     Several techniques for preparing ZnO nanoparticles have been developed. The intensity of the visible luminescence of the ZnO colloids prepared using these methods is remarkably high.

    In this study, the preparation of ZnO nanoparticles in an amphiphilic N,N-dimethylacrylamide (DMAA) gel was investigated. Furthermore, the stability of the ZnO colloidal nanoparticles formed in the gel network was examined along with the capability of size control at the nanosized level by the synthesis composition of the gel.